Nanostructured layers in high temperature-pressure treated silicon implanted with helium

Barbara Surma 2,3Andrzej Misiuk 2Vito Raineri 1Artur Wnuk 3M. Prujszczyk 2Andrzej Bukowski 3,4

1. CNR-IMETEM (CNR-IMETEM), Stradale Primosole 50, Catania I-95121, Italy
2. Institute of Electron Technology (ITE), al. Lotników 32/46, Warszawa 02-668, Poland
3. Institute of Electronic Materials Technology (ITME), Wólczyńska 133, Warszawa 01-919, Poland
4. CEMAT Silicon, Wólczyńska 133, Warszawa 01-919, Poland

Abstract

Helium- and hydrogen- implanted single crystalline silicon have become of remarkable technological interest because of importance of He- and / or H2- filled microcavities created at annealing in Si:He and Si:H for producing the gettering active areas and for Si wafer splitting (Smart Cut process). The estimated pressure in the He/H2 filled bubbles is in the Giga Pascal (GPa) range [1] and defects of different kind and concentrations are created in annealed Si:He and Si:H. The shear stress at the H/He bubble / Si matrix boundary can be tuned by annealing the Si:H, Si:He and Si:H,He samples under enhanced hydrostatic pressure of inert gas ambient (HT-HP treatment [2]). The HT-HP treatment results, between others, in the decreased strain between the Si matrix and the He- or H -containing nanostructured layers and in creation of more numerous defects in Si:He [2,3]. The effect of HT-HP treatment on Si:He (prepared by Si implantation with He+ at energy, E, up to 300 keV, doses, D, up to '1x1017'cm'{-2}' at up to 1270 K under hydrostatic Ar pressure up to 1.2 GPa was investigated in the present work by photoluminescence (PL), X-Ray, TEM and related methods. Among others it has been stated that enhanced HP at annealing of Fz-Si:He (E = 150 keV, D='2x1016'cm'{-2}' at 1070-1270 K results in modified structure of the buried nanostructured layer promoting creation of dislocations (enhanced intensity of dislocation-related D1 PL line) and point defects clusters. Also the recently obtained results concerning the HT-HP treatment effect on Si:H,He structures will be presented and discussed.
Our investigations are currently supported (at 2002 - 2004) by the Polish Committee for Scientific Research (grant no. 4T08A 03423).

1. Xiang Lu, et al., Appl. Phys. Lett. 71 (1997) 1804.
2. A.Misiuk, et. al., Mater. Phys. Mech. 5 (2002) 31.
3. A.Misiuk, et al., Comput. Mater. Sci. 21 (2001) 515.

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Presentation: oral at E-MRS Fall Meeting 2003, Symposium F, by Andrzej Misiuk
See On-line Journal of E-MRS Fall Meeting 2003

Submitted: 2003-05-07 11:02
Revised:   2003-08-21 15:12
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