Self-organized metallodielectric eutectic nanoparticle based composite material: manufacturing and properties
|Katarzyna Sadecka , Marcin Gajc , Andrzej Kłos , Barbara Surma , Dorota A. Pawlak|
Institute of Electronic Materials Technology (ITME), Warszawa 01919, Poland
Metallodielectric composites are very interesting from the point of view of metamaterials and plasmonics. Bottom-up methods, like self-organization and other chemical methods are potential future manufacturing techniques which could be suitable for large scale fabrication [1, 2, 3, 4].
The main idea of the work is to utilize the self-organization mechanism of metallodielectric eutectic materials to create plasmonic nanocomposites trough directional solidification.
In this work Bi2O3-Ag eutectic directionally solidified by the micro-pulling down method has been studied. The composite exhibits three-dimensional silver multiscale structure embedded in the bismuth oxide matrix. After applied annealing procedure in the Bi2O3-Ag composite the metallic nanoparticles are formed and material exhibits a localized surface plasmon resonance (LSPR) at around 590nm, which has been confirmed by the UV-VIS transmission spectra. This is the first demonstration of plasmonic behaviour in a eutectic which has been engineered specifically for this purpose using the self-organization mechanism.
The study of an influence of annealing temperature of the composite on the resonance properties in comparison with the pure bismuth oxide phase, together with micro/nano-structural investigation (XRD, SEM, TEM) will be presented. Additionally after doping the material with erbium ions, the enhancement of the luminescence at the telecommunication wavelength is observed.
 D. A. Pawlak, S. Turczynski, M. Gajc, et al., How far are we from making metamaterials by self-organization? The microstructure of highly anisotropic particles with an SRR-like geometry. Adv. Funct. Mat. 20, 1116, (2010).
 M. Gajc, B. H. Surma, A. Klos, K. Sadecka, K. Orlinski, A. E. Nikolaenko, K. Zdunek, D. A. Pawlak, Nanoparticle Direct Doping: novel method for manufacturing three-dimensional bulk plasmonic nanocomposites. Adv. Funct. Mat. 10.1002/adfm.201203116 (2013)
 C. Rockstuhl, T. Scharf, A metamaterial based on coupled metallic nanoparticles and its band-gap property, J. Microsc, 229, 2, 281, (2008).
 N.I. Zheludev, The Road Ahead for Metamaterials, Science, 328, 582, (2010).
Presentation: Poster at 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17, Topical Session 9, by Katarzyna Sadecka
See On-line Journal of 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17
Submitted: 2013-05-22 21:43 Revised: 2013-05-22 21:47