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Eu0.55Sr0.45MnO3 and Sm0.55Sr0.45MnO3 manganites. Comparison of properties

Anna I. Abramovich 

M.V. Lomonosov Moscow State University, Vorobyevy gory, Moscow 119992, Russian Federation

Abstract

We have studied magnetic, elastic, and transport properties of Eu0.55Sr0.45MnO3 (1) and Sm0.55Sr0.45MnO3 (2) ceramic. For (1) the resistivity ρ shows an insulating behaviour even at 4.2 K. Near TC a break on the ρ(T) dependence and on the temperature dependence of linear thermal expansion was observed for (1) and the sharp maximum on the ρ(T) dependence and sharp volume change ΔV/V ~ 0.1% was observed for (2). For (1) in the wide temperature region from 4.2 K to T >> TC the sharp jump of magnetization σ, volume magnetostriction ω, and ρ takes place at HC1 < H < HC2, i.e. under magnetic field action the phase transition from insulating AFM-like state to metallic FM-like state occurs. σ(H) curves are not saturated at H > HC2 up to 80 kOe. The maximal value of σ is less than one corresponding FM ordering of Mn3+ and Mn4+ ions, namely 70% from latter at 4.2 K under 80 kOe. The metallic FM-like state was unchanged after field removing. Such behaviour is observed within temperature interval from 4.2 to 50 K. At temperatures from 50 to 120 K the jump of σ, ω, and ρ is maintained, but shape of σ(H), ω(H), and ρ(H) curves is changed and sample return in original state after field removing. The value of HC decreases with increasing T within first and increases within second interval. For (2) sharp jump of σ, ω, and ρ takes place at HC1 < H < HC2 at T > TC only, and their saturation is achieved at H > HC2. For (1) MR is positive at H < HC1 and reaches of 6% value, at H > HC1 MR becomes negative and reaches of 105 %. ω is negative and giant for both compounds and is observed from 4.2 K to T >> TC for (1) and in the TC region only for (2). We consider that differnt types of inhomogeneous magnetic state are realized in our compounds and reason of CMR and giant ω is the increase of FM phase volume under field action.

 

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Presentation: poster at E-MRS Fall Meeting 2003, Symposium D, by Anna I. Abramovich
See On-line Journal of E-MRS Fall Meeting 2003

Submitted: 2003-05-26 18:52
Revised:   2009-06-08 12:55