Search for New Metallic Glass Compositions in NiZrTi Base Alloys Near Multicomponent Eutectic Positions

Jan M. Dutkiewicz 1Jerzy Morgiel Lidia Lityńska-Dobrzyńska Wojciech Maziarz 1Tomasz Czeppe 1Magdalena Parra Carillo 

1. Polish Academy of Sciences, Institute of Metallurgy and Materials Sciences (IMIM PAN), Reymonta 25, Kraków 30-059, Poland

Abstract

In a new metallic glasses near muticomponent eutectic compositions even a small composition changes have a significant effect on the Tg and Tx temperatures and therefore on the glass forming ability. In the present study the alloy of composition Ni25Cu25Zr25Ti25 (1 in at%) was melt spun amorphous. The position of the eutectic was identified as Ni29.2Cu29.9Zr17Ti24.9 (2) and the melt spun ribbon shows a better glass forming ability than the alloy (1) as manifested by DT and Tg/Tl increase. The alloy (2) was modified by manganese addition as Ti25Zr20Ni22,5Cu22,5Mn10 (3). In this alloy the eutectic was identified at Ti21Zr14Ni27Cu27Mn7 (4) and as melt spun has shown slightly better Tg/Tl.=0.63 as compared to 0.62 in the alloy (3). A second copper rich eutectic was also identified in this alloy near Ti16Zr14Ni24Cu39Mn7 (5). Nickel rich alloy of the composition Ni60Nb15Zr15Ti10 shows the eutectic composition at Ni48,5Nb21,5-Ti16.5Zr13,5 (6). The alloy (6) has been modified by silicon addition with the eutectic composition containing Ni50.3Nb14.4-Ti17.3Zr15.1Si2.8 (7). Glass forming ability was studied in NiCuZrTiAlSi alloys. The composition of the eutectic was found near Ni45.5Cu10.5Zr20Ti15-Al3.5Si5.5 (8). Present studies indicate that eutectic 4-6 component alloys lead to the increase of the Tg/Tl and DT coefficients in the melt spun amorphous ribbons.

Presentation: Oral at E-MRS Fall Meeting 2006, Symposium I, by Jan M. Dutkiewicz
See On-line Journal of E-MRS Fall Meeting 2006
Submitted: 2006-05-16 14:12
Revised:   2006-05-16 14:12
Related papers
  1. Microstructure and magnetic properties of two phase b+g ferromagnetic Co-Ni-Al alloys
  2. Influence of hydrogen on hydrogenated cadmium telluride optical spectra
  3. Characterization and properties of a modified NiTi shape memory alloy by N^{+} ion implantation.
  4. Reconstruction of lattice structure of ion-implanted near-surface regions of HgCdTe epitaxial layers
  5. Microstructure changes in two phase β+γ Co-Ni-Al ferromagnetic shape memory alloys in relation to Al/Co ratio
  6. HRTEM and TEM studies of amorphous structures in ZrNiTiCu base alloys obtained by rapid solidification or ball milling
  7. Powder metallurgy technology of NiTi shape memory alloy
  8. TEM Characterization of Thin-Layered Materials
  9. Effect of Directional Crystallization Rate on Microtexture of Al-CuAl_{2} Eutectic Alloy
  10. The role of radiation defects in HgCdTe epitaxial growth
  11. Interface dynamics of melt instabilities on semiconductor surfaces
  12. Influence of hydrogen on optical spectra of hydrogenated CdTe
  13. Phase and structural transformations in Ti-Ta alloys in wide region of compositions
  14. Microstructure and micro mechanical properties of multilayer Cr/CrN, PLD coatings
  15. Sequence of phases formations in Al-Mg-Si alloy with Sc and Zr addition during heat treatment
  16. Nanocrystalline materials manufactured by torsion under pressure of 2 GPa
  17. Structure and mechanical properties of ball milled TiAl-Cr intermetallics consolidated by hot pressing and pulse plasma sintering
  18. Multi- layer composite based on amorphous materials and quasicrystals, deposited by laser ablation
  19. Nanocrystalline TiAl-V intermetallics hot pressed from mechanically alloyed powders
  20. Nanocrystallization and mechanical properties of the amorphous Ni-Zr-Ti -Al-Cu -Si ribbons.
Google
 
Web science24.com
© 1998-2008 pielaszek research, all rights reserved Powered by the Conference Engine