Synchrotron topographic studies of domain structure in Czochralski grown PrxLa1-xAlO3 crystals

Krzysztof Wieteska 1Wojciech Wierzchowski 2Agnieszka Malinowska 2Sebastian Turczynski 2Maria Lefeld-Sosnowska 3Dorota A. Pawlak 2Tadeusz Łukasiewicz 2Carsten Paulmann 4

1. Institute of Atomic Energy POLATOM, Świerk 05-400, Poland
2. Institute of Electronic Materials Technology (ITME), Wólczyńska 133, Warszawa 01-919, Poland
3. Warsaw University, Institute of Experimental Physics (IEP UW), Hoża 69, Warszawa 00-681, Poland
4. University of Hamburg, Mineralogisch-Pertographisches Institut, Hamburg, Germany

Abstract

The real structure of Prx La1-x AlO3  (x = 1, 0.75, 0.55, 0.4 and 0) and LaAlO3 doped with Pr single crystals was characterized with a number of methods including conventional and synchrotron X-ray diffraction topography, and polariscopic micrography. The surface of the samples  has been also investigated with a high resolution profilometer.

The crystals were grown by Czochralski technique [1]. High purity Pr6O11, Al2O3 and La2O3 oxides (99.995%) were used as raw materials. All components were mixed in stoichiometric ratios. The pulling and rotation rates were in the range of 1-1.7mm/h and 6-8 rpm. The crystals have been grown in pure nitrogen atmosphere. The samples were cut out perpendicularly to the <100> pseudo-cubic axis closest to the actual growth direction.

The presently applied sample orientation allowed precise recognition of domain systems, and determination of the orientation of the lattice connected with the domains.

It has been confirmed that the domains are of a twin character, similar as it was described by Dudley and Yao in LaAlO3 and LaGaO3 crystals [2]. In those crystals the twin configuration and their changes were studied as a function of temperature in the vicinity of phase transition temperatures .

The domain systems, observed by us, were investigated in PrxLa1-xAlO3 (for different x) and in LaAlO3 crystals doped with Pr , and their appearance and configuration were compared for samples, containing different amount of Praseodymium. The observed twin domains systems were located along <100> and <110> (pseudo-cubic) directions. The evaluated changes of the lattice orientation depend on the chemical composition of the samples. The representative back-reflection white beam synchrotron radiation topograph of the LaAlO3  crystal is shown in Fig.1. The important advantage of the white beam transmission section topography was the possibility of proving that the domain systems are perpendicular to the sample surface (Fig.2).

The details of the domain structure were well revealed in polariscopic micrographs. It was also possible to reveal them by means of the profilometer. The observed surface relief is most probably caused by different mechanical or chemical polishing of differently oriented materials inside the domains.

 Fig1.jpg

 

Figure 1. The representative projection back-reflection topograph of the LaAlO3 revealing the domain structures along two perpendicular planes.

 Fig2.jpg

 

Figure 2. The transmission white beam section topograph of the LaAlO3. The vertical location of the domains proves their perpendicularity to the surface of the sample.

The synchrotron investigations were supported by the HASYLAB project II-20060165 EC.

 

References

[1] S. Turczynski, K. Orliński, D. A. Pawlak, R. Diduszko, J. Mucha, M. Pekala, , J.F. Fagnard, Ph. Vanderbemden, M.A. Carpenter, Cryst. Growth & Design. 11 (2011) 1091-1097.

[2] M. Dudley, G-D Yao: J. Phys. D: 26 (1993) A120-A125.

 

 

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Presentation: Poster at IX Krajowe Sympozjum Użytkowników Promieniowania Synchrotronowego, by Agnieszka Malinowska
See On-line Journal of IX Krajowe Sympozjum Użytkowników Promieniowania Synchrotronowego

Submitted: 2011-06-15 13:11
Revised:   2011-09-13 17:17