Rietveld refinement of powder diffraction data collected with a laboratory diffractometer equipped with a linear X-ray detector

Wojciech Paszkowicz 

Polish Academy of Sciences, Institute of Physics, al. Lotników 32/46, Warszawa 02-668, Poland

Abstract

Advantages of using a strip detector in the X-ray Bragg-Brentano diffraction geometry are presented. The instrument setting (described in detail in [1]) includes a semiconductor strip detector permitting for data collection with high counting rate and very good resolution. The installed detector (of construction related to those earlier reported [2-5]) is a commercial one with 127 active strips of 0.05 mm width. The X-ray beam is conditioned by selecting either an X-ray filter or a Johansson-monochromator. The latter option offers a high spectral purity and low background at the expense of reduced intensity. Nevertheless, the data collection using this setting is several times faster than that available at classical instruments. The data reveal peaks of even 0.1%~intensity, enabling i) improved analysis results for minority phases in bulk polycrystalline samples, ii) detailed phase analysis of very thin polycrystalline layers and iii) diffraction studies of multilayer systems. The diffraction data of polycrystals are suitable for structure refinement by the Rietveld refinement. Refinement applications for various materials will be demonstrated. The applied modification of the Bragg-Brentano setting is concluded to create new quality in diffraction measurements.

[1] Paszkowicz W, Proc. XIX Conf. on Applied Crystallography (Kraków 1-4 Sept. 2003), ed. H. Morawiec and D. Stróż (World Scientific, Singapore 2004), pp. 22-26.
[2] Zieba A, Dabrowski W, Grybos P, Powroznik W, Stobiecki T, Swientek K, Slowik J., Wiacek P., Acta Phys. Polon. 101 (2002) 629-634
[3] Fauth F, Bronnimann C, Auderset H, Maehlum G, Pattison P, Patterson B, Nucl. Instrum. Meth. A 439 (2000) 138-146
[4] Loukas D, Psycharis V, Karvelas E, Pavlidis A, Haralabidis N, Mousa J, IEEE Trans. Nucl. Sci. 47 (2000) 877-880
[5] Schmitt B, Bronnimann C, Eikenberry EF, Hulsen G, Toyokawa H, Horisberger R, Gozzo F, Patterson B, Schulze-Briese C, Tomizaki T, Nucl. Instrum. Meth. A 518 (2004) 436-439

Related papers
  1. Pressure dependence of lattice parameter of Gadolinium Gallium Garnet crystals
  2. Lattice parameters of hard materials in the low-temperature range
  3. Lattice parameters of a wurtzite-type (Zn,Mg)Se crystal as a function of temperature
  4. Rietveld refinement for Li2Si2O5 doped with vanadium
  5. High-pressure diffraction study of α and β Ge3N4
  6. Effect of annealing on the structure and microstructure of Pr doped ZrO2-Y2O3 nanocrystals
  7. ZnO thin films for organic/inorganic heterojunctions
  8. Optimisation of parameters of a dynamic penalty function for a test example of powder pattern indexing
  9. Wide band-gap II-VI semiconductors for optoelectronic applications
  10. Low temperature ZnMnO by ALD
  11. Substrate effect on the ground state of the magnetic order in NSMO/YBCO superlattices
  12. Method of Manganese co-doping of LT ZnO films
  13. Ferromagnetism in ZnO:Mn thin films deposited by PEMOCVD
  14. Structure properties of bulk ZnO crystals
  15. Magnetic anisotropy and structural properties of ferromagnet/MgO/ferromagnet system
  16. Rietveld refinement for polycrystalline indium nitride
  17. LATTICE PARAMETERS OF INDIUM NITRIDE IN THE 22-310 K TEMPERATURE RANGE
  18. Promising high quality short period Fe/Fe-N multilayers deposited by the sputtering
  19. Structural and Magnetic Properties of Cr/Gd Multilayers Deposited on Sapphire and MgO Substrates
  20. X-ray diffraction studies of thermal-expansion with the use of 1D detectors installed at synchrotron beamlines
  21. Sensitivity of a genetic algorithm to the mutation rate parameter value: results for a crystallographic test
  22. Phase relationships in annealed Cu-Al-O layers
  23. Growth and characterization of thin films of ZnO by Atomic Layer Epitaxy
  24. Area detector as a tool to study properties of the magnetic multilayers by the neutron scattering
  25. Influence of hydrogen adsorption on magnetic properties of Fe films and multilayers
  26. Transmission electron microscopy and X-ray diffraction study of α'-Al2 CO crystals
  27. Diamond as X-ray Wavelength Standard for Thermal-Expansion Studies Using Synchrotron Sources
  28. X-Ray Study of Lattice Parameters of GaN in a Broad Temperature Range

Presentation: poster at E-MRS Fall Meeting 2004, Symposium D, by Wojciech Paszkowicz
See On-line Journal of E-MRS Fall Meeting 2004

Submitted: 2004-06-02 18:47
Revised:   2004-07-15 15:16
Google
 
Web science24.com
© 1998-2008 pielaszek research, all rights reserved Powered by the Conference Engine