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Influence of silicas and microfillers from recycling materials on strength of epoxypolymer

Dmitry L. Starokadomsky 

Institute of Surface Chemistry (ISC), 17 General Naumov, Kyiv 03164, Ukraine

Abstract

The influence of silicas (A-50, A-100, A-300, titanaerosil TAS) and recycling-fillers from polymers (PET, PS, epoxy), wood sawdust,  brick dust on strength properties of polymer from epoxyresin ED-20 (+ 12,5 wt% PolyethylenePolyamine) were investigated.

It is shown, that addition of 2 wt% of silicas cause to increase tensile strength of F1 (plastic deformation) as well as F2 (finally destruction). Increasing of F1 is proportional to surface area of silica: F1 grows up to 3% for A-50, up to 4% for A-100 and up to 7% for A-300 (fig.2). It is shown increasing of F2 up to 7-18% without obvious correlation with surface area of silica. The influence of silicas to tearing strength Q is various. In the same manner, Q grows proportionally to the surface area of silica. The micro-hardness M demonstrates small increasing after addition of 2 wt% of silicas.

Addition of microfillers may be effective for reinforcing in several cases. Hence, addition of ruthil (TiO2) does not change values of F1, F2 and Q (growth to 3-3,5%). In the same time addition of epoxypolymer-poudre may increase tensile strength . Addition of PET may increase micro-hardness M .

Thus, principal possibility to improving of epoxycomposite’s properties by addition of unmodified silicas and recycling-fillers was shown.

 

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Presentation: Poster at E-MRS Fall Meeting 2009, Symposium I, by Dmitry L. Starokadomsky
See On-line Journal of E-MRS Fall Meeting 2009

Submitted: 2009-05-26 06:32
Revised:   2009-06-09 12:55