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Synthesis and characterization of nitrogen doped TiO2 aerogels

Virginia V. Danciu 1Zsolt Pap 1Lucian Baia 2Florin Vasiliu 3Lucian Diamandescu 3Veronica Cosoveanu 1Monica Baia 2

1. Babes-Bolyai University, Arany Janos 11, Cluj-Napoca 400028, Romania
2. Babes-Bolyai University, Faculty of Physics, M. Kogalniceanu 1, Cluj-Napoca 400084, Romania
3. National institute for Materials physics (NIMP), Atomistilor 105 bis, Bucharest 77125, Romania

Abstract

Titania based aerogels are a special class of porous solid materials with high surface area, ultra-low density and high homogeneity that make them attractive for various applications in solar energy conversion, pigments and electronic devices as well as in (photo)catalysis [1].

Nitrogen doped TiO2 aerogels prepared by different chemical routes are studied by various physical investigation techniques (Brunauer–Emmet–Teller (BET), Transmission Electron Microscopy (TEM), Selected Area Electron Diffraction (SAED), X-ray diffraction (XRD) and Raman spectroscopy) in order to get valuable information concerning the morphology and the structure of the newly prepared porous materials. The catalytic activity of the nitrogen doped TiO2 aerogels was determined by measuring the degradation rate of the salicylic acid used as reference organic material. The correlations between the morphological and structural parameters and those obtained from the photocatalytic activity assessment are discussed

References

[1]. Z. Zhu, L. Y. Tsung, M. Tomkiewicz, J. Phys. Chem., 99, 1995, 15945-15949.

 

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Presentation: Poster at E-MRS Fall Meeting 2007, Symposium B, by Monica Baia
See On-line Journal of E-MRS Fall Meeting 2007

Submitted: 2007-05-11 12:24
Revised:   2009-06-07 00:44